Insights into the mechanism and selectivity of the Rh(<scp>i</scp>)-catalyzed cycloisomerization reaction of benzylallene-alkynes involving C–H bond activation-Reference-Cited by-同舟云学术

Insights into the mechanism and selectivity of the Rh(i)-catalyzed cycloisomerization reaction of benzylallene-alkynes involving C–H bond activation

Published:2023 Issue:1 Volume:10 Page:115-126
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Ren Ying¹^ORCID,Yang Tilong²^ORCID,Lin Zhenyang²^ORCID

Affiliation:

1. Key Laboratory of Magnetic Molecules & Magnetic Information Materials Ministry of Education, The School of Chemistry and Material Science, Shanxi Normal University, Taiyuan, China

2. Department of Chemistry, The Hong Kong University of Science and Technology, Clear Water Bay, Kowloon, Hong Kong, China

Abstract

The detailed reaction mechanisms of rhodium-catalyzed cycloisomerization of benzylallene-terminal alkynes involving Csp2−H bond activation on the benzyl phenyl ring have been investigated with the aid of density functional theory calculations.

Funder

National Natural Science Foundation of China

Program for the Scientific Activities of Selected Returned Overseas Professionals in Shaanxi Province

Research Grants Council, University Grants Committee

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D2QO01503J

Reference54 articles.

1. C–H activation