Ordering by cation replacement in the system Na2−xLixGa7

Author:

Yu Chia-Chi1,Prots Yurii1,Ormeci Alim1,Krnel Mitja1ORCID,Schmidt Marcus1,Akselrud Lev12,Wagner Frank R.1ORCID,Grin Yuri1,Baitinger Michael1ORCID

Affiliation:

1. Max-Planck-Institut für Chemische Physik fester Stoffe, Nöthnitzer Str. 40, 01187 Dresden, Germany

2. Ivan Franko Lviv National University, Kyryla i Mefodia St. 6, 29005 Lviv, Ukraine

Abstract

The Zintl–Wade phase Na1Li1Ga7 introduces a novel variant within the MgB12Si2 structure family. The substitution of Na atoms with Li in Na2Ga7 results in a distinct and fully ordered cation arrangement.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Cited by 2 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. Na2B6Si2: A Prototype Silico-boride with Closo (B6)2– Clusters;Journal of the American Chemical Society;2024-08-26

2. The Solubility of Indium in Na2Ga7;European Journal of Inorganic Chemistry;2024-05-23

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