Nickel-catalyzed direct methylation of arylphosphines <i>via</i> carbon–phosphorus bond cleavage using AlMe<sub>3</sub>-Reference-Cited by-同舟云学术

Nickel-catalyzed direct methylation of arylphosphines via carbon–phosphorus bond cleavage using AlMe₃

Published:2023 Issue:64 Volume:59 Page:9722-9725
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Igarashi Takuya¹,Shimazumi Ryoma¹,Chatani Naoto¹²^ORCID,Tobisu Mamoru¹³^ORCID

Affiliation:

1. Department of Applied Chemistry, Graduate School of Engineering, Osaka University, Suita, Osaka 565-0871, Japan

2. Research Center for Environmental Preservation), Osaka University, Suita, Osaka 565-0871, Japan

3. Innovative Catalysis Science Division, Institute for Open and Transdisciplinary Research Initiatives (ICS-OTRI), Osaka University, Suita, Osaka 565-0871, Japan

Abstract

Ni-catalyzed direct substitution of an aryl group of arylphosphines with a methyl group is developed using AlMe3. This reaction proceeds via the cleavage of unactivated C–P bonds, and phosphine oxides and sulfides can also be methylated directly.

Funder

Japan Society for the Promotion of Science

Japan Science and Technology Corporation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/CC/D3CC02455E

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5. Three-Component Coupling of Acyl Fluorides, Silyl Enol Ethers, and Alkynes by P(III)/P(V) Catalysis

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