Room temperature hydrophosphination using a simple iron salen pre-catalyst

Author:

Gallagher K. J.1234,Webster R. L.1234

Affiliation:

1. Department of Chemistry

2. University of Bath

3. Claverton Down

4. Bath, UK

Abstract

A highly active iron(iii) complex for room temperature hydrophosphination is reported. The products of the hydrophosphination reaction are also useful ligands for iron catalyzed Negishi cross-coupling.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference42 articles.

1. A. Behr , Applied homogeneous catalysis , Wiley-VCH , Weinheim , 2012

2. T. Reetz , Organocatalysis , Springer-Verlag , Berlin , 2008

3. J.-P. Majoral , New Aspects in Phosphorus Chemistry V , Springer , Berlin , 2005

4. Contemporary avenues in catalytic PH bond addition reaction: A case study of hydrophosphination

5. V. P. Ananikov and M.Tanaka , Topics in Organometallic Chemistry: Hydrofunctionalization , Springer , Heidelberg , 2013

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