Electrochemical oxidative dehydrogenation of hydrosilanes to generate silyl radicals: an efficient method for the construction of Si–O/Si–Si bonds utilizing a recyclable ionic liquid catalyst-Reference-Cited by-同舟云学术

Electrochemical oxidative dehydrogenation of hydrosilanes to generate silyl radicals: an efficient method for the construction of Si–O/Si–Si bonds utilizing a recyclable ionic liquid catalyst

Published:2024 Issue: Volume: Page:
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Wei Zhaoxin¹,Chen Ziren¹^ORCID,Xue Fei¹,Yue Yuancheng¹,Wu Shaofeng¹,Zhang Yonghong¹^ORCID,Wang Bin¹^ORCID,Xia Yu¹^ORCID,Jin Weiwei²^ORCID,Liu Chenjiang¹^ORCID

Affiliation:

1. State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources, Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education & Xinjiang Uygur Autonomous Region, Urumqi Key Laboratory of Green Catalysis and Synthesis Technology, College of Chemistry, Xinjiang University, Urumqi 830017, P. R. China

2. Key Laboratory of Specialty Agri-product Quality and Hazard Controlling Technology of Zhejiang Province, College of Life Sciences, China Jiliang University, Hangzhou 310018, P. R. China

Abstract

A highly efficient and sustainable approach was developed for the construction of Si–O/Si–Si bonds, through the electrochemical oxidative dehydrogenation of hydrosilanes with O-nucleophiles or self-condensation of hydrosilanes.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Xinjiang Province

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/GC/D4GC02663B

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