[CuII{(LISQ)˙−}2] (H2L: thioether-appended o-aminophenol ligand) monocation triggers change in donor site from N2O2 to N2O(2)S and valence-tautomerism-Reference-Cited by-同舟云学术

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[CuII{(LISQ)˙−}2] (H2L: thioether-appended o-aminophenol ligand) monocation triggers change in donor site from N2O2 to N2O(2)S and valence-tautomerism

Published:2019 Issue:5 Volume:48 Page:1795-1813
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Rajput Amit¹²³⁴⁵,Saha Anannya⁶⁷⁸⁴,Barman Suman K.¹²³⁴,Lloret Francesc⁹¹⁰¹¹¹²¹³,Mukherjee Rabindranath¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Indian Institute of Technology Kanpur

3. Kanpur 208 016

4. India

5. Department of Basic and Applied Sciences

6. Department of Chemical Sciences

7. Indian Institute of Science Education and Research Kolkata

8. Mohanpur 741 246

9. Departament de Quımíca

10. Inorgànica/Instituto de Ciencia Molecular (ICMOL)

11. Universitat de Valeńcia

12. Polígono de la Coma

13. 46980-Paterna

Abstract

The complex [Cu^II{(L^ISQ)˙⁻}₂]·CH₂Cl₂ and its 1e⁻ oxidized form are synthesized and structurally characterized; temperature-induced equilibrium, involving [Cu^II{(L^ISQ)˙⁻}{(L^IBQ)⁰}](PF₆) ⇌ [Cu^I{(L^IBQ)⁰}₂](PF₆) is observed.

Funder

Department of Science and Technology, Ministry of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C8DT03778G

Reference127 articles.

1. Preface: Forum on Redox-Active Ligands

2. Preface for the Forum on Applications of Metal Complexes with Ligand-Centered Radicals

3. New avenues for ligand-mediated processes – expanding metal reactivity by the use of redox-active catechol, o-aminophenol and o-phenylenediamine ligands

4. Transition metal complexes with bulky 4,6-di-tert-butyl-N-aryl(alkyl)-o-iminobenzoquinonato ligands: Structure, EPR and magnetism

5. Non-innocent ligands

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1. Ni(ii) and Pd(ii) complexes of a new redox-active pentadentate azo-appended 2-aminophenol ligand: Pd(ii)-assisted intraligand cyclization forms a phenoxazinyl ring;Dalton Transactions;2024

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3. Iron(III) Complexes of a Hexadentate Thioether-Appended 2-Aminophenol Ligand: Redox-Driven Spin State Switchover;Inorganic Chemistry;2022-03-21

4. Ni(ii) complexes of a new tetradentate NN′N′′O picolinoyl-1,2-phenylenediamide-phenolate redox-active ligand at different redox levels;Dalton Transactions;2022

5. Switchover from NiIIN2O2 to NiIIN2O2S2 coordination triggered by the redox behaviour of a non-innocent 2-aminophenolate ligand;Journal of Chemical Sciences;2021-10-22

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