PM-IRRAS and DFT investigation of the surface orientation of new Ir piano-stool complexes attached to Au(111)-Reference-Cited by-同舟云学术

PM-IRRAS and DFT investigation of the surface orientation of new Ir piano-stool complexes attached to Au(111)

Published:2022 Issue:46 Volume:51 Page:17688-17699
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Miller Christopher J.¹^ORCID,Brunner Felix M.¹,Kelly H. Ray²,Cheung Po Ling¹,Torquato Nicole A.¹,Gembicky Milan¹^ORCID,Okuno Saya¹,Chan Thomas¹,Batista Victor S.²,Kubiak Clifford P.¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of California, San Diego, 9500 Gilman Drive, Mail Code 0358, La Jolla, California 92093-0358, USA

2. Department of Chemistry and Energy Sciences Institute, Yale University, 225 Prospect Street, New Haven, Connecticut 06520, USA

Abstract

Detailed characterization and understanding of Ir piano-stool catalysts immobilized on gold surfaces are a necessary first step in understanding new heterogenized catalytic systems at interfaces.

Funder

National Science Foundation

Air Force Office of Scientific Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT02730E

Reference70 articles.

1. Mechanistic basis for tuning iridium hydride photochemistry from H2 evolution to hydride transfer hydrodechlorination

2. Molecular Photoelectrocatalysts for Visible Light-Driven Hydrogen Evolution from Neutral Water

3. H2 Evolution at an Electrochemical “Underpotential” with an Iridium-Based Molecular Photoelectrocatalyst

4. Molecular Photoelectrocatalysts for Light-Driven Hydrogen Production

5. Photochemical Formic Acid Dehydrogenation by Iridium Complexes: Understanding Mechanism and Overcoming Deactivation

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