Are one-step aromatic nucleophilic substitutions of non-activated benzenes concerted processes?-Reference-Cited by-同舟云学术

Are one-step aromatic nucleophilic substitutions of non-activated benzenes concerted processes?

Published:2019 Issue:35 Volume:17 Page:8185-8193
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Domingo Luis R.¹²³⁴⁵^ORCID,Ríos-Gutiérrez Mar¹²³⁴⁵^ORCID,Chamorro Eduardo⁶⁷⁸⁹¹⁰^ORCID,Pérez Patricia⁶⁷⁸⁹¹⁰^ORCID

Affiliation:

1. Department of Organic Chemistry

2. Research Building Jeroni Muñoz

3. University of Valencia

4. Valencia

5. Spain

6. Universidad Andres Bello

7. Facultad de Ciencias Exactas

8. Departamento de Ciencias Químicas

9. Computational and Theoretical Chemistry Group

10. 8370146 Santiago

Abstract

Analysis of the mechanism of one-step S_NAr reactions of non-activated benzenes shows the presence of structures similar to those of Meisenheimer intermediates, thus accounting for the non-concerted nature of these reactions.

Funder

Ministerio de Ciencia y Tecnología

Fondo Nacional de Desarrollo Científico y Tecnológico

Horizon 2020

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/OB/C9OB01589B

Reference42 articles.

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4. Rate-Determining Factors in Nucleophilic Aromatic Substitution Reactions

5. F. Terrier , Modern Nucleophilic Aromatic Substitution 1-94 , Wiley , 2013

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