Azadipyrromethene cyclometalation in neutral RuII complexes: photosensitizers with extended near-infrared absorption for solar energy conversion applications

Author:

Bessette André12345,Cibian Mihaela1234,Ferreira Janaina G.1234,DiMarco Brian N.6789,Bélanger Francis5104,Désilets Denis5104,Meyer Gerald J.6789,Hanan Garry S.1234

Affiliation:

1. Département de Chimie

2. Université de Montréal

3. Montréal

4. Canada

5. PCAS Canada Inc. (http://www.pcas.com)

6. Departments of Chemistry and Materials Science & Engineering

7. The University of North Carolina at Chapel Hill

8. Chapel Hill

9. USA

10. Québec

Abstract

In the on-going quest to harvest near-infrared (NIR) photons for energy conversion applications, a novel family of neutral ruthenium(ii) sensitizers has been developed by cyclometalation of an azadipyrromethene chromophore.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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