Crystalline sulfur-functionalized poly(α-olefin) synthesized by scandium-catalyzed coordination polymerization-Reference-Cited by-同舟云学术

Crystalline sulfur-functionalized poly(α-olefin) synthesized by scandium-catalyzed coordination polymerization

Published:2022 Issue:17 Volume:13 Page:2477-2483
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Liu Zhao-Xuan¹^ORCID,Xu Tie-Qi¹^ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals, Department of Chemistry, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

Abstract

Combined with organoborate, the scandium complex catalyzed monomers to produce a series of syndiotactic sulfur-functionalized poly(α-olefin)s (rrrr of up to 0.95) which formed crystalline materials with a Tm of up to 91 °C.

Funder

Fundamental Research Funds for the Central Universities

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2022/PY/D2PY00315E

Reference44 articles.

1. Frontiers in Olefin Polymerization: Reinventing the World’s Most Common Synthetic Polymers

2. Coordination Polymerization of Polar Vinyl Monomers by Single-Site Metal Catalysts