Scandium bis(trimethylsilyl)methyl complexes revisited: extending the 45Sc NMR chemical shift range and a new structural motif of Li[CH(SiMe3)2]
Author:
Affiliation:
1. Institut für Anorganische Chemie
2. Eberhard Karls Universität Tübingen
3. D-72076 Tübingen
4. Germany
Abstract
Scandium mixed alkyls form readily via subsequent treatment of ScCl3 with Li[CH(SiMe3)2] and LiMe, as probed by 45Sc NMR spectroscopy.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/DT/D0DT01247E
Reference90 articles.
1. CYCLOPENTADIENYL COMPOUNDS OF Sc, Y, La, Ce AND SOME LANTHANIDE ELEMENTS
2. The Long Search for Stable Transition Metal Alkyls
3. Stable homoleptic metal alkyls
4. Metal .sigma.-hydrocarbyls, MRn. Stoichiometry, structures, stabilities, and thermal decomposition pathways
Cited by 15 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献
1. Rare‐Earth‐Metal Alkyl and Aryl Compounds in Organic Synthesis;European Journal of Inorganic Chemistry;2024-05-23
2. In situ generation of organocalcium compounds for a calcium-based Grignard-type chemistry;Dalton Transactions;2024
3. Putting on the Crown: Synthesis and Reactivity of Trimethyltitanium;Organometallics;2023-03-14
4. Sc and Y Heteroalkyl and Alkyl-Hydrido Complexes Containing Diphenylmethanide Ligands [2,2′-(4-MeC6H3NMe2)2CH]−;Organometallics;2023-03-02
5. Mixed Methyl/Chlorido Yttrium(III) Complexes Supported by a Neutral Tridentate N-Donor Ligand;Organometallics;2023-02-28
1.学者识别学者识别
2.学术分析学术分析
3.人才评估人才评估
"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370
www.globalauthorid.com
TOP
Copyright © 2019-2024 北京同舟云网络信息技术有限公司 京公网安备11010802033243号 京ICP备18003416号-3