Oxidation of benzyl alcohol catalyzed by gold nanoparticles under alkaline conditions: weak vs. strong bases
Author:
Affiliation:
1. Departamento de Química Fundamental
2. Instituto de Química
3. Universidade de São Paulo
4. São Paulo
5. Brazil
6. Laboratório Nacional de Nanotecnologia
7. CNPEM/ABTLuS
8. Campinas
Abstract
A comparative study of the promotion effect of weak and strong bases in the aqueous oxidation of benzyl alcohol by Au/TiO2 showed that better conversion and aldehyde selectivity can be obtained using weak bases.
Funder
São Paulo Research Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA01795A
Reference55 articles.
1. M. B. Smith and J.March, in March's Advanced Organic Chemistry, John Wiley & Sons, Inc., 2006, pp. 1703–1869
2. Catalytic Oxidation: Principles and Applications, ed., R. A. Sheldon and R. A. V. Santen, World Scientific Pub Co Inc, Singapore, River Edge, NJ, 1996
3. Supported gold nanoparticles as catalysts for organic reactions
4. Oxidation of Alcohols with Molecular Oxygen on Solid Catalysts
5. Selective oxidation using gold
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