Mechanism of phase transfer of uranyl ions: a vibrational sum frequency generation spectroscopy study on solvent extraction in nuclear reprocessing
Author:
Affiliation:
1. Nuclear Science and Engineering Center
2. Japan Atomic Energy Agency (JAEA)
3. Tokai
4. Japan
Abstract
VSFG study on interfaces of TBP/uranyl aqueous solutions shows that uranyl ion does not form complexes with TBP at the interface, and proposes a new extraction mechanism.
Funder
Japan Society for the Promotion of Science
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CP/C8CP04558E
Reference14 articles.
1. Recent advances on the chemistry of solvent extraction applied to the reprocessing of spent nuclear fuels and radioactive wastes
2. Molecular Dynamics Simulations of the Structure and Thermodynamics of Carrier-Assisted Uranyl Ion Extraction
3. Uranyl nitrate complex extraction into TBP/dodecane organic solutions: a molecular dynamics study
4. Liquid–Liquid Extraction of Uranyl by TBP: The TBP and Ions Models and Related Interfacial Features Revisited by MD and PMF Simulations
5. Passage of TBP–uranyl complexes from aqueous–organic interface to the organic phase: insights from molecular dynamics simulation
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