Pressure-induced valence transition in the mixed-valence (Sm1/3Ca2/3)2.75C60 fulleride

Author:

Yoshikane Naoya12345ORCID,Matsui Keisuke12345ORCID,Nakagawa Takeshi678ORCID,Terzidou Anastasia G. V.9101112ORCID,Takabayashi Yasuhiro131415516ORCID,Yamaoka Hitoshi17185ORCID,Hiraoka Nozomu192021,Ishii Hirofumi192021,Arvanitidis John9101112ORCID,Prassides Kosmas12345ORCID

Affiliation:

1. Department of Materials Science

2. Graduate School of Engineering

3. Osaka Prefecture University

4. Osaka 599-8531

5. Japan

6. Center for High-Pressure Science & Technology Advanced Research

7. 100094 Beijing

8. P. R. China

9. Physics Department

10. Aristotle University of Thessaloniki

11. 54124 Thessaloniki

12. Greece

13. WPI-Advanced Institute for Materials Research (WPI-AIMR)

14. Tohoku University

15. Sendai 980-8577

16. Department of Physical Science and Engineering

17. RIKEN SPring-8 Center

18. Sayo

19. National Synchrotron Radiation Research Center

20. Hsinchu 30076

21. Taiwan

Abstract

The mixed-valence (Sm1/3Ca2/3)2.75C60 fulleride undergoes an abrupt strongly hysteretic reversible phase transition accompanied by a drastic increase in the bulk Sm valence by ∼20% to +2.71 through the application of external pressure.

Funder

Hellenic Foundation for Research and Innovation

Japan Society for the Promotion of Science

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Materials Science

Reference39 articles.

1. Mixed valency in rare-earth fullerides

2. Unconventional high- T c superconductivity in fullerides

3. P. Wachter , Intermediate valence and heavy fermions , in Handbook on the physics and chemistry of rare earths , ed. K. A. Gschneidner , L. Eyring , G. H. Lander and G. R. Chopin , Elsevier Science B. V ., Amsterdam , 1994 , vol. 19, pp. 177–388

4. The Disorder-Free Non-BCS Superconductor Cs 3 C 60 Emerges from an Antiferromagnetic Insulator Parent State

5. Upper critical field reaches 90 tesla near the Mott transition in fulleride superconductors

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