Fast and reversible insertion of carbon dioxide into zirconocene–alkoxide bonds. A mechanistic study-Reference-Cited by-同舟云学术

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Fast and reversible insertion of carbon dioxide into zirconocene–alkoxide bonds. A mechanistic study

Published:2014 Issue:23 Volume:43 Page:8894-8898
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Brink Alice¹²³⁴¹,Truedsson Ida⁴¹⁵⁶,Fleckhaus André⁴¹⁵⁶,Johnson Magnus T.⁴¹⁵⁶,Norrby Per Ola⁷⁸⁹¹⁰¹¹,Roodt Andreas¹²³,Wendt Ola F.⁴¹⁵⁶

Affiliation:

1. Department of Chemistry

2. University of the Free State

3. Bloemfontein 9300, South Africa

4. Centre for Analysis and Synthesis

5. Lund University

6. S-221 00 Lund, Sweden

7. Pharmaceutical Development

8. Global Medicines Development

9. AstraZeneca

10. SE-431 83 Mölndal, Sweden

11. Department of Chemistry and Molecular Biology

Abstract

In two consecutive equilibria the compound (Cp*)₂Zr(OMe)₂ undergoes insertion of CO₂ to form the mono- and bis-hemicarbonates with a high rate.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT53566E

Reference44 articles.

1. Utilisation of CO2 as a chemical feedstock: opportunities and challenges

2. Transformation of Carbon Dioxide

3. Transition Metal Catalyzed Reactions of Carbon Dioxide and Other Heterocumulenes

4. Transformation of Carbon Dioxide with Homogeneous Transition-Metal Catalysts: A Molecular Solution to a Global Challenge?

5. The Chemistry of Dimethyl Carbonate

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3. Countercation Effect on CO 2 Binding to Oxo Titanate with Bulky Anilide Ligands;Chemistry – A European Journal;2018-10-23

4. Mechanism of generation of closo-decaborato amidrazones. Intramolecular non-covalent B–H⋯π(Ph) interaction determines stabilization of the configuration around the amidrazone CN bond;New Journal of Chemistry;2018

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