The mechanism of copper-catalyzed oxytrifluoromethylation of allylamines with CO2: a computational study-Reference-Cited by-同舟云学术

The mechanism of copper-catalyzed oxytrifluoromethylation of allylamines with CO2: a computational study

Published:2018 Issue:4 Volume:5 Page:633-639
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Zhu Lei¹²³⁴,Ye Jian-Heng⁵⁶⁷⁸⁴,Duan Meng¹²³⁴,Qi Xiaotian¹²³⁴,Yu Da-Gang⁵⁶⁷⁸⁴^ORCID,Bai Ruopeng¹²³⁴^ORCID,Lan Yu¹²³⁴⁹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Chongqing University

3. Chongqing

4. China

5. Key Laboratory of Green Chemistry & Technology of Ministry of Education

6. College of Chemistry

7. Sichuan University

8. Chengdu

9. College of Chemistry and Molecular Engineering

Abstract

We propose a novel Cu(i)–Cu(ii) catalytic cycle for the copper-catalyzed oxytrifluoromethylation of allylamines with CO₂, which proceeds through a radical–radical cross-coupling pathway.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/QO/C7QO00838D

Reference83 articles.

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