Abnormal copper coordination obtained by a TiO<sub>2</sub> overlayer as the key to enhance photocatalytic hydrogen generation-Reference-Cited by-同舟云学术

Abnormal copper coordination obtained by a TiO₂ overlayer as the key to enhance photocatalytic hydrogen generation

Published:2024 Issue:30 Volume:12 Page:19236-19246
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Quach Vien-Duong¹^ORCID,Spadaro Maria Chiara²³^ORCID,Dragoe Diana⁴,Botifoll Marc²^ORCID,Vezin Hervé⁵,Colbeau-Justin Christophe¹,Dumeignil Franck⁶^ORCID,Arbiol Jordi²⁷^ORCID,Wojcieszak Robert⁶^ORCID,Ghazzal Mohamed Nawfal¹^ORCID

Affiliation:

1. Université Paris-Saclay, CNRS UMR 8000, Institut de Chimie Physique, F-91405 Orsay, France

2. Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC, BIST, Campus UAB, Bellaterra, ES-08193 Barcelona, Catalonia, Spain

3. Department of Physics and Astronomy “Ettore Majorana”, CNR-IMM, University of Catania, via S. Sofia 64, Catania 95123, Italy

4. Université Paris-Saclay, CNRS UMR 8182, Institut de Chimie Moléculaire et des Matériaux d'Orsay, F-91405 Orsay, France

5. LASIRE – Laboratoire Avancé de Spectroscopie pour les Interactions la Réactivité et l'environnement, Université de Lille, CNRS UMR 8516, F-59000 Lille, France

6. UCCS – Unité de Catalyse et Chimie du Solide, Université de Lille, CNRS UMR 8181, F-59000 Lille, France

7. ICREA, Pg. Lluís Companys 23, ES-08010 Barcelona, Catalonia, Spain

Abstract

TiO2 overlayer induces the formation of four-coordinated copper(ii) species surrounded by oxygen atoms, enhancing charge transfer and photocatalytic activity.

Funder

Generalitat de Catalunya

Universitat Autònoma de Barcelona

Agence Nationale de la Recherche

Centres de Recerca de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D4TA03072A

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5. Electrochemical Photolysis of Water at a Semiconductor Electrode