Mechanistic in situ investigation of heterogeneous hydrogenation over Rh/TiO2 catalysts: selectivity, pairwise route and catalyst nature
Author:
Affiliation:
1. Laboratory of Magnetic Resonance Microimaging
2. International Tomography Center SB RAS
3. 630090 Novosibirsk
4. Russia
5. Novosibirsk State University
6. Boreskov Institute of Catalysis SB RAS
Abstract
We report a catalyst with the highest selectivity toward pairwise hydrogen addition of 7% among supported metal catalysts, found as a result of variation of Rh/TiO2 catalyst preparation procedures.
Funder
Russian Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/FD/C9FD00138G
Reference39 articles.
1. E. M. M. Viviente , P. S. S.Pregosin and D.Schott , in Mechanisms in Homogeneous Catalysis: A Spectroscopic Approach , Wiley-VCH Verlag GmbH & Co. KGaA , 2005 , pp. 1–80
2. Kinetics of Asymmetric Transfer Hydrogenation, Catalyst Deactivation, and Inhibition with Noyori Complexes As Revealed by Real-Time High-Resolution FlowNMR Spectroscopy
3. S. Stapf and S. I. I.Han , NMR Imaging in Chemical Engineering , Wiley , 2006
4. Magnetic resonance imaging methods for in situ studies in heterogeneous catalysis
5. In situ magnetic resonance visualisation of the spatial variation of catalytic conversion within a fixed-bed reactor
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