Mechanistic in situ investigation of heterogeneous hydrogenation over Rh/TiO2 catalysts: selectivity, pairwise route and catalyst nature

Author:

Pokochueva Ekaterina V.12345ORCID,Burueva Dudari B.12345ORCID,Kovtunova Larisa M.63453ORCID,Bukhtiyarov Andrey V.63453ORCID,Gladky Alexei Yu.634ORCID,Kovtunov Kirill V.12345ORCID,Koptyug Igor V.12346ORCID,Bukhtiyarov Valerii I.63453ORCID

Affiliation:

1. Laboratory of Magnetic Resonance Microimaging

2. International Tomography Center SB RAS

3. 630090 Novosibirsk

4. Russia

5. Novosibirsk State University

6. Boreskov Institute of Catalysis SB RAS

Abstract

We report a catalyst with the highest selectivity toward pairwise hydrogen addition of 7% among supported metal catalysts, found as a result of variation of Rh/TiO2 catalyst preparation procedures.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Reference39 articles.

1. E. M. M. Viviente , P. S. S.Pregosin and D.Schott , in Mechanisms in Homogeneous Catalysis: A Spectroscopic Approach , Wiley-VCH Verlag GmbH & Co. KGaA , 2005 , pp. 1–80

2. Kinetics of Asymmetric Transfer Hydrogenation, Catalyst Deactivation, and Inhibition with Noyori Complexes As Revealed by Real-Time High-Resolution FlowNMR Spectroscopy

3. S. Stapf and S. I. I.Han , NMR Imaging in Chemical Engineering , Wiley , 2006

4. Magnetic resonance imaging methods for in situ studies in heterogeneous catalysis

5. In situ magnetic resonance visualisation of the spatial variation of catalytic conversion within a fixed-bed reactor

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3