Chameleonic metal-bound isocyanides: a π-donating Cu<sup>I</sup>-center imparts nucleophilicity to the isocyanide carbon toward halogen bonding-Reference-Cited by-同舟云学术

Chameleonic metal-bound isocyanides: a π-donating Cu^I-center imparts nucleophilicity to the isocyanide carbon toward halogen bonding

Published:2022 Issue:8 Volume:9 Page:1655-1665
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Kinzhalov Mikhail A.¹^ORCID,Ivanov Daniil M.¹,Melekhova Anna A.¹,Bokach Nadezhda A.¹^ORCID,Gomila Rosa M.²^ORCID,Frontera Antonio²^ORCID,Kukushkin Vadim Yu.¹³^ORCID

Affiliation:

1. Saint Petersburg State University, 199034 Saint Petersburg, Russian Federation

2. Department of Chemistry, Universitat de les Illes Balears, 07122 Palma de Mallorca, Baleares, Spain

3. Laboratory of Crystal Engineering of Functional Materials, South Ural State University, 76, Lenin Av., 454080 Chelyabinsk, Russian Federation

Abstract

Two adjacent CuI-bound isocyanide groups exhibit nucleophilic properties induced by a π-donating d10[CuI] center and function as an integrated two-center halogen bond acceptor forming bifurcated μ2-X⋯(C,C) halogen bonds.

Funder

Russian Science Foundation

Federación Española de Enfermedades Raras

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D2QI00034B

Reference108 articles.

1. Halogen Bonding in Supramolecular Chemistry

2. Halogen bonding in polymer science: from crystal engineering to functional supramolecular polymers and materials