Persistent four-coordinate iron-centered radical stabilized by π-donation-Reference-Cited by-同舟云学术

Persistent four-coordinate iron-centered radical stabilized by π-donation

Published:2016 Issue:1 Volume:7 Page:191-198
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Sunada Yusuke¹²³⁴,Ishida Shintaro⁵⁶⁷⁸⁴,Hirakawa Fumiya⁵⁶⁷⁸⁴,Shiota Yoshihito¹²⁹⁴,Yoshizawa Kazunari¹²⁹⁴,Kanegawa Shinji¹²⁹⁴,Sato Osamu¹²⁹⁴,Nagashima Hideo¹²³⁴¹⁰,Iwamoto Takeaki⁵⁶⁷⁸⁴

Affiliation:

1. Institute for Materials Chemistry and Engineering

2. Kyushu University

3. Kasuga

4. Japan

5. Department of Chemistry

6. Graduate School of Science

7. Tohoku University

8. Sendai 980-8578

9. Nishi-ku

10. CREST

Abstract

Generation of four-coordinate iron-centered radical3was realized by the thermal homolysis of the unsupported Fe–Fe bond of2.

Funder

Ministry of Education, Culture, Sports, Science, and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/SC/C5SC02601F

Reference88 articles.

1. Seventeen-electron metal-centered radicals

2. Photochemistry of metal-metal bonds

3. Photochemical disproportionation of metalmetal bonded carbonyl dimers

4. 19-Electron organometallic adducts

5. RADICAL PATHWAYS IN REACTIONS OF TRANSITION METAL ORGANOMETALLIC COMPOUNDS

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