2-Adamantylidene and its heavier analogues: hyperconjugation versus lone pair stability and electrophilicity versus nucleophilicity
Author:
Affiliation:
1. Theoretical and Computational Chemistry Laboratory
2. Department of Chemistry
3. National Institute of Technology Calicut
4. Kozhikode
5. India
Abstract
Too heavy to bend: The Cieplak-type hyperconjugative interaction mainly contributes to the stability of 2C and 2Si whereas the inertness of lone pairs is the major factor for 2Ge and 2Sn. These molecules (2X; X = C–Sn) can be classified as a class of ambiphilic compounds.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C4DT03801K
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