Functional transformation of four-bladed rylene propellers utilizing non-metal and d8 metal core shifting strategy: significant impact on photovoltaic performance and electrocatalytic hydrogen evolution activity

Author:

Han Jianhua12345,Shi Wenwen67389,Wang Xunchang12345,Cai Jingwen1011125,Hao Xinyu1011125,Shi Jingying67389ORCID,Bao Xichang12345ORCID,Yang Renqiang12345ORCID

Affiliation:

1. CAS Key Laboratory of Bio-Based Materials

2. Qingdao Institute of Bioenergy and Bioprocess Technology

3. Chinese Academy of Sciences

4. Qingdao 266101

5. China

6. State Key Laboratory of Catalysis

7. Dalian Institute of Chemical Physics

8. Dalian National Laboratory for Clean Energy

9. Dalian 116023

10. State Key Laboratory of Fine Chemicals

11. Dalian University of Technology

12. Dalian 116024

Abstract

Six four-bladed rylene propellers with d8 metal and non-metal core are synthesized. By utilizing core transformations, both highly efficient organic solar cell and electrochemical water splitting for H2 evolution are achieved for PDI propellers.

Funder

National Natural Science Foundation of China

Youth Innovation Promotion Association of the Chinese Academy of Sciences

Natural Science Foundation of Shandong Province

Dalian Institute of Chemical Physics

Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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