Highly 3,4-selective living polymerization of 2-phenyl-1,3-butadiene with amidino N-heterocyclic carbene ligated rare-earth metal bis(alkyl) complexes-Reference-Cited by-同舟云学术

Highly 3,4-selective living polymerization of 2-phenyl-1,3-butadiene with amidino N-heterocyclic carbene ligated rare-earth metal bis(alkyl) complexes

Published:2015 Issue:113 Volume:5 Page:93507-93512
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Yao Changguang¹²³⁴⁵,Xie Hongyan¹²³⁴⁵,Cui Dongmei¹²³⁴⁵

Affiliation:

1. State Key Laboratory of Polymer Physics and Chemistry

2. Changchun Institute of Applied Chemistry

3. Chinese Academy of Sciences

4. Changchun 130022

5. China

Abstract

2-Phenyl-1,3-butadiene was polymerized using an amidino N-heterocyclic carbene lutetium bis(alkyl) precursor in high 3,4-selectivity (96.9%) and a living mode to afford a new plastic polydiene with a high T_g of 56.1 °C.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA18713C

Reference37 articles.

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