Degradation pathways of a highly active iron(iii) tetra-NHC epoxidation catalyst-Reference-Cited by-同舟云学术

Degradation pathways of a highly active iron(iii) tetra-NHC epoxidation catalyst

Published:2021 Issue:3 Volume:11 Page:795-799
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Dyckhoff Florian¹²³⁴,Schlagintweit Jonas F.¹²³⁴^ORCID,Bernd Marco A.¹²³⁴^ORCID,Jakob Christian H. G.¹²³⁴,Schlachta Tim P.¹²³⁴^ORCID,Hofmann Benjamin J.¹²³⁴^ORCID,Reich Robert M.¹²³⁴^ORCID,Kühn Fritz E.¹²³⁴^ORCID

Affiliation:

1. Molecular Catalysis, Catalysis Research Center and Department of Chemistry

2. Technische Universität München

3. 85748 Garching bei München

4. Germany

Abstract

Elucidation of different decomposition pathways of a highly active tetradentate iron–NHC epoxidation catalyst reveals direct carbene oxidation to be the decisive cause of catalyst degradation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D0CY02433C

Reference56 articles.

1. Sustainability in Catalytic Oxidation: An Alternative Approach or a Structural Evolution?

2. Epoxidation of olefins with homogeneous catalysts – quo vadis?

3. Molecular Epoxidation Reactions Catalyzed by Rhenium, Molybdenum, and Iron Complexes

4. Fluorinated Solvents in Methyltrioxorhenium‐Catalyzed Olefin Epoxidations

5. Synthesis and characterization of novel cyclopentadienyl molybdenum imidazo[1,5-a]pyridine-3-ylidene complexes and their application in olefin epoxidation catalysis

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