Nitrogen-enriched flexible metal–organic framework for CO<sub>2</sub> adsorption-Reference-Cited by-同舟云学术

Nitrogen-enriched flexible metal–organic framework for CO₂ adsorption

Published:2024 Issue:33 Volume:53 Page:14028-14036
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lancheros Andrés¹²³^ORCID,Goswami Subhadip³^ORCID,Zarate Ximena⁴,Schott Eduardo¹²^ORCID,Hupp Joseph T.³^ORCID

Affiliation:

1. Department of Inorganic Chemistry, Faculty of Chemistry and Pharmacy, UC Energy Center, Center for Research in Nanotechnology and Advanced Materials (CIEN-UC), Pontificia Universidad Católica de Chile, Av. Vicuña Mackenna 4860, Santiago, Chile

2. ANID – Millennium Science Initiative Program – Millennium Nuclei on Catalytic Process Towards Sustainable Chemistry (CSC), Chile

3. Department of Chemistry and International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208, USA

4. Institute of Applied Sciences, Faculty of Engineering, Universidad Autónoma de Chile, Av. Pedro de Valdivia 425, Santiago, Chile

Abstract

A novel MOF [Zn2(L)(DMF)] was synthesized showing high crystallinity and stability up to 250 °C. Its nitrogen-rich pyrazole linkers enable good CO2 adsorption with a low isosteric enthalpy. Adsorption results were validated by DFT calculations.

Funder

Fondo Nacional de Desarrollo Científico y Tecnológico

U.S. Department of Energy

Fondo de Financiamiento de Centros de Investigación en Áreas Prioritarias

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT01457J

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