Axial zero-field splitting in mononuclear Co(ii) 2-N substituted N-confused porphyrin: Co(2-NC3H5-21-Y-CH2C6H4CH3-NCTPP)Cl (Y = o, m, p) and Co(2-NC3H5-21-CH2C6H5-NCTPP)Cl

Author:

Lai Ya-Yuan1234,Chang Yu-Chang1234,Chen Jyh-Horung1234,Wang Shin-Shin5674,Tung Jo-Yu89104

Affiliation:

1. Department of Chemistry

2. National Chung Hsing University

3. Taichung 40227

4. Taiwan

5. Material and Chemical Research Laboratories

6. ITRI

7. Hsin-Chu 300

8. Department of Occupational Safety and Health

9. Chung Hwai University of Medical Technology

10. Tainan 717

Abstract

Four inner C-benzyl and C-xylyl-substituted cobalt(ii) complexes of a 2-N-substituted N-confused porphyrin were synthesized and the D-parameter is related to the structural parameters of the cobalt(ii) complexes.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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