Nonadditive ion effects on the coil–globule equilibrium of PNIPAM: a computer simulation study

Author:

Zhao Yani1ORCID,Bharadwaj Swaminath1ORCID,van der Vegt Nico F. A.1ORCID

Affiliation:

1. Eduard-Zintl-Institut für Anorganische und Physikalische Chemie, Technische Universität Darmstadt, Alarich-Weiss-Strasse 10, 64287 Darmstadt, Germany

Abstract

Nonadditive ion effects on the coil–globule equilibrium of PNIPAM arise due to the interplay between the depletion of the strongly hydrated sulfate ions and the preferential binding of the iodide ions on the polymer.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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