Synthesis and full characterization of an iridium B–H activation intermediate of the monocarba-closo-dodecaborate anion

Author:

Shen Yunjun1234,Pan Yani1234,Liu Jiyong1234,Sattasathuchana Tosaporn1567,Baldridge Kim K.89104,Duttwyler Simon1234

Affiliation:

1. Department of Chemistry

2. Zhejiang University

3. 310027 Hangzhou

4. P. R. China

5. University of Zurich

6. 8057 Zurich

7. Switzerland

8. School of Pharmaceutical Science and Technology

9. Tianjin University

10. 300072 Tianjin

Abstract

The preparation and characterization of an iridium complex of the monocarba-closo-dodecaborate anion is reported. It was prepared by B–H bond activation using a tosyl amide directing group.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference80 articles.

1. R. N. Grimes , Carboranes, Elsevier, Amsterdam, 2nd edn, 2011

2. N. S. Hosmane , Boron Science: New Technologies and Applications, Taylor & Francis Books/CRC, Boca Raton, FL, 2011

3. Carboranes:  A New Class of Weakly Coordinating Anions for Strong Electrophiles, Oxidants, and Superacids

4. Update 1 of:Chemistry of the Carba-closo-dodecaborate(−) Anion, CB11H12–

5. C. Knapp , Weakly Coordinating Anions: Halogenated Borates and Dodecaborates, Comprehensive Inorganic Chemistry II, Elsevier, Amsterdam, 2013, vol. 1, pp. 651–679

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