Bio-inspired single-chain polymeric nanoparticles containing a chiral salen TiIV complex for highly enantioselective sulfoxidation in water-Reference-Cited by-同舟云学术

Bio-inspired single-chain polymeric nanoparticles containing a chiral salen TiIV complex for highly enantioselective sulfoxidation in water

Published:2017 Issue:4 Volume:19 Page:1182-1193
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Zhang Yaoyao¹²³⁴⁵,Tan Rong¹²³⁴⁵^ORCID,Gao Mengqiao¹²³⁴⁵,Hao Pengbo¹²³⁴⁵,Yin Donghong¹²³⁴⁵

Affiliation:

1. Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education)

2. National & Local Joint Engineering Laboratory for New Petro-chemical Materials and Fine Utilization of Resources

3. Hunan Normal University

4. Changsha 410081

5. P. R. China

Abstract

Bio-inspired SCPNs containing a chiral salen Ti^IV complex in the IL-mediated hydrophobic cavity exhibited enzyme-mimetic activity, especially, outstanding selectivity, and facile reusability in enantioselective sulfoxidation in water.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/GC/C6GC02743A

Reference49 articles.

1. Highly enantioselective oxidation of cyclic dithioacetals by using a Ti(salen) and urea·hydrogen peroxide system

2. Metallocene Sulfoxides as Precursors of Metallocenes with Planar Chirality

3. Mechanistic Studies on a Sulfoxide Transfer Reaction Mediated by Diphenyl Sulfoxide/Triflic Anhydride

4. Metal-catalyzed asymmetric sulfoxidation, epoxidation and hydroxylation by hydrogen peroxide

5. A chiral porous metallosalan-organic framework containing titanium-oxo clusters for enantioselective catalytic sulfoxidation

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