TiO2-Modulated tetra(4-carboxyphenyl)porphyrin/perylene diimide organic Z-scheme nano-heterojunctions for efficient visible-light catalytic CO2 reduction

Author:

Wang Yilin1,Zhao Zhenlong1,Sun Rui2,Bian Ji1ORCID,Zhang Ziqing1,Jing Liqiang12ORCID

Affiliation:

1. Key Laboratory of Functional Inorganic Materials Chemistry (Ministry of Education), School of Chemistry and Materials Science, International Joint Research Center for Catalytic Technology, Heilongjiang University, Harbin 150080, P. R. China

2. Key Lab of Groundwater Resources and Environment of Ministry of Education, Key Lab of Water Resources and Aquatic Environment of Jilin Province, College of New Energy and Environment, Jilin University, Changchun 130012, P. R. China

Abstract

A cascade Z-scheme nano-heterojunction of TiO2 incorporated TCPP/PDI with full spectrum response is constructed for efficient CO2 reduction, in which the energy platform TiO2 directs charge transfer by inhibiting the pathway as that in a type II one.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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