The [Ag25Cu4H8Br6(CCPh)12(PPh3)12]3+ : Ag13H8 silver hydride core protected by [CuAg3(CCPh)3(PPh3)3]+ motifs
Author:
Affiliation:
1. Department of Chemistry
2. Graduate School of Science
3. Hiroshima University
4. Higashi-hiroshima 739-8526
5. Japan
Abstract
Four trigonal-planar [CuAg3(CCAr)3(PPh3)3]+ units linked by halogen ions cover a polyhydride–Ag cluster Ag13H8 to form the core–shell Ag nanoclusters formulated as [Ag13H8X6{CuAg3(CCAr)3(PPh3)3}4]3+ (X = Cl, Br; Ar = Ph, Tol).
Funder
Ministry of Education, Culture, Sports, Science and Technology
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00294E
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