Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2-Reference-Cited by-同舟云学术

Solvent-dependent nuclearity, geometry and catalytic activity of [(SPhos)Pd(Ph)Cl]2

Published:2017 Issue:22 Volume:46 Page:7223-7231
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Brazier John B.¹²³⁴,Newton Mark A.⁵⁶⁷⁴,Barreiro Elena M.¹²³⁴^ORCID,Adrio Luis A.¹²³⁴^ORCID,Naya Leticia⁸⁹¹⁰⁴^ORCID,Hii King Kuok (Mimi)¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Imperial College London

3. London SW7 2AZ

4. UK

5. Department of Physics

6. University of Warwick

7. Coventry

8. Prometic Bioseparations

9. Horizon Park

10. Cambridge CB23 7AJ

Abstract

The nuclearity and structures of the palladium complex [(SPhos)Pd(Ph)Cl]₂ in the solid and solution states are revisited using a combination of Extended X-ray Absorption Fine Structure (EXAFS) spectroscopy, NMR spectroscopy, mass spectrometry, DFT calculations and trapping experiments.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT01019B

Reference33 articles.

1. Profound Steric Control of Reactivity in Aryl Halide Addition to Bisphosphane Palladium(0) Complexes

2. Oxidative Addition to Palladium(0) Diphosphine Complexes: Observations of Mechanistic Complexity with Iodobenzene as Reactant

3. Oxidative Addition of Haloheteroarenes to Palladium(0): Concerted versus SNAr-Type Mechanism