Real-time observation of the exchange process between H<sub>2</sub>O and NO in the metal–organic framework Ni-MOF-74-Reference-Cited by-同舟云学术

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Real-time observation of the exchange process between H₂O and NO in the metal–organic framework Ni-MOF-74

Published:2024 Issue:12 Volume:12 Page:6880-6884
ISSN:2050-7488
Container-title:Journal of Materials Chemistry A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Pandey Haardik¹^ORCID,Wang Hao²,Alfaro Monica Vasquez³,Li Jing²^ORCID,Thonhauser Timo¹^ORCID,Tan Kui⁴^ORCID

Affiliation:

1. Department of Physics and Center for Functional Materials, Wake Forest University, Winston-Salem, NC 27109, USA

2. Department of Chemistry and Chemical Biology, Rutgers University, Piscataway, NJ 08854, USA

3. Department of Materials Science & Engineering, University of Texas at Dallas, Richardson, Texas 75080, USA

4. Department of Chemistry, University of North Texas, Denton, TX 76203, USA

Abstract

Combination of in situ IR spectroscopy and ab initio calculations reveals the detailed exchange process of H2O and NO in Ni-MOF-74 and uncovers its unusual energetics and kinetics caused by H-bonding interaction.

Funder

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/TA/D3TA05265F

Reference37 articles.

1. Metal–Organic Frameworks for Separations

2. Microporous Metal-Organic Framework Materials for Gas Separation

3. Metal–Organic Frameworks for Separation

4. Hydrocarbon Separations in a Metal-Organic Framework with Open Iron(II) Coordination Sites

5. Synergistic sorbent separation for one-step ethylene purification from a four-component mixture

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