GeClx[Co(CO)3PR3]4−x (x = 0–3; R = nPr, nBu): from cobalt substituted germanes to novel binary cluster compounds.-Reference-Cited by-同舟云学术

GeClx[Co(CO)3PR3]4−x (x = 0–3; R = nPr, nBu): from cobalt substituted germanes to novel binary cluster compounds.

Published:2021 Issue:31 Volume:50 Page:10789-10797
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Preißing Lars¹²³⁴,Behling Elias¹²³⁴,Schnepf Andreas¹²³⁴^ORCID

Affiliation:

1. Institut für Anorganische Chemie

2. Universität Tübingen

3. D-72076 Tübingen

4. Germany

Abstract

The synthesis of cobalt substituted germanes of the composition GeCl_x[Co(CO)₃PR₃]_4−x (x = 0–3; R = ⁿPr, ⁿBu) is presented. Reductive coupling with different reducing agents leads amongst others to the pseudo-cubic cluster compound Ge₇Co(CO)₃[Co(CO)₃PⁿBu₃]₇.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02016A

Reference34 articles.

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4. Zur Kenntnis der Reaktionen des Kobalttetracarbonyls mit verschiedenartigen Basen, VI. Über triphenylphosphinhaltige Kobaltcarbonyle

5. Trimethylstannane derivatives of cobalt(I); synthesis and NMR spectroscopy. The crystal structures of [Co(Me3Sn)(CO)3L] (L = PPh3, AsPh3)

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