Rigid versions of PDTA4− incorporating a 1,3-diaminocyclobutyl spacer for Mn2+ complexation: stability, water exchange dynamics and relaxivity-Reference-Cited by-同舟云学术

Rigid versions of PDTA4− incorporating a 1,3-diaminocyclobutyl spacer for Mn2+ complexation: stability, water exchange dynamics and relaxivity

Published:2021 Issue:44 Volume:50 Page:16290-16303
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Uzal-Varela Rocío¹^ORCID,Lalli Daniela²^ORCID,Brandariz Isabel¹,Rodríguez-Rodríguez Aurora¹^ORCID,Platas-Iglesias Carlos¹^ORCID,Botta Mauro²^ORCID,Esteban-Gómez David¹^ORCID

Affiliation:

1. Universidade da Coruña, Centro de Investigacións Científicas Avanzadas (CICA) and Departamento de Química, Facultade de Ciencias, 15071, A Coruña, Galicia, Spain

2. Magnetic Resonance Platform (PRISMA-UPO), Dipartimento di Scienze e Innovazione Tecnologica, Università del Piemonte Orientale “A. Avogadro”, Viale T. Michel 11, 15121 Alessandria, Italy

Abstract

Increasing the rigidity of the six-membered chelate ring of [Mn(PDTA)]2− has a significant impact in the hydration number, relaxivity, stability and inertness of the complex.

Funder

Ministerio de Ciencia e Innovación

Xunta de Galicia

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02498A

Reference95 articles.

1. Chemistry of MRI Contrast Agents: Current Challenges and New Frontiers

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