Enthalpy of formation and thermodynamic insights into yttrium doped BaZrO3-Reference-Cited by-同舟云学术

Enthalpy of formation and thermodynamic insights into yttrium doped BaZrO3

Published:2014 Issue:42 Volume:2 Page:17840-17847
ISSN:2050-7488
Container-title:J. Mater. Chem. A
language:en
Short-container-title:J. Mater. Chem. A

Author:

Gonçalves M. D.¹²³⁴⁵,Maram P. S.¹²³,Muccillo R.⁴⁵⁶⁷⁸,Navrotsky A.¹²³

Affiliation:

1. Peter A. Rock Thermochemistry Laboratory and NEAT ORU

2. University of California

3. Davis, USA

4. Center of Science and Technology of Materials

5. Energy and Nuclear Research Institute

6. Travessa R 400

7. Cidade Universitária

8. S. Paulo, Brazil

Abstract

This work brings insights into the defect chemistry of YBZ solid solutions by measuring enthalpies of formation. We find a correlation between the obtained thermodynamic data and the known trend of the proton conductivity of YBZ solid solutions. This study is important for informed thermodynamic history-based materials selection and processing for specific applications.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/TA/C4TA03487B

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3. High Total Proton Conductivity in Large-Grained Yttrium-Doped Barium Zirconate