Rare-earth alkyl complexes supported by formamidinate ligands: synthesis, structure, and catalytic activity for isoprene polymerization
Author:
Affiliation:
1. Laboratory of Functionalized Molecular Solids
2. Ministry of Education
3. Anhui Laboratory of Molecule-Based Materials
4. School of Chemistry and Materials Science
5. Anhui Normal University
Abstract
Monoalkyl rare-earth metal complexes could be highly active catalysts for 1,4-regioselective polymerization of isoprene in the presence of cocatalysts.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT00242C
Reference34 articles.
1. Advances in the Coordination Chemistry of Amidinate and Guanidinate Ligands
2. Lanthanide amidinates and guanidinates in catalysis and materials science: a continuing success story
3. Rare earth metal bis(amide) complexes bearing amidinate ancillary ligands: Synthesis, characterization, and performance as catalyst precursors for cis-1,4 selective polymerization of isoprene
4. Ytterbium amides of linked bis(amidinate): synthesis, molecular structures, and reactivity for the polymerization of l-lactide
5. Binuclear rare-earth polyhydride complexes bearing both terminal and bridging hydride ligands
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