Steric effect of the dithiolato linker on the reduction mechanism of [Fe2(CO)6{μ-(XCH2)2CRR′}] hydrogenase models (X = S, Se)-Reference-Cited by-同舟云学术

Steric effect of the dithiolato linker on the reduction mechanism of [Fe2(CO)6{μ-(XCH2)2CRR′}] hydrogenase models (X = S, Se)

Published:2015 Issue:43 Volume:44 Page:18780-18794
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Trautwein Ralf¹²³⁴,Almazahreh Laith R.¹²³⁴,Görls Helmar¹²³⁴,Weigand Wolfgang¹²³⁴⁵

Affiliation:

1. Institut für Anorganische und Analytische Chemie

2. Friedrich-Schiller-Universität Jena

3. D-07743 Jena

4. Germany

5. Jena Center of Soft Matter (JCSM)

Abstract

Investigations of the electrochemical properties of [Fe₂(CO)₆{μ-(XCH₂)₂CRR′}] (X = S, Se; R or R′ = H or Me) showed that the complex with the bulkiest CMe₂moiety undergoes reduction with potential inversion.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01387A

Reference93 articles.

1. Occurrence, Classification, and Biological Function of Hydrogenases: An Overview

2. Hydrogenases and the Global H 2 Cycle

3. Further characterization of the [Fe]-hydrogenase from Desulfovibrio desulfuricans ATCC 7757

4. Hydrogenases: Hydrogen-Activating Enzymes

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