Magnetic and structural properties of dinuclear singly bridged-phenoxido metal(ii) complexes

Author:

Massoud Salah S.1234,Spell Mark1234,Ledet Catherine C.1234,Junk Thomas1234,Herchel Radovan56789ORCID,Fischer Roland C.10111213,Trávníček Zdeněk56789,Mautner Franz A.14111513

Affiliation:

1. Department of Chemistry

2. University of Louisiana at Lafayette

3. Lafayette

4. USA

5. Department of Inorganic Chemistry & Regional Centre of Advanced Technologies and Materials

6. Faculty of Science

7. Palacký University

8. CZ-77146 Olomouc

9. Czech Republic

10. Institut für Anorganische Chemische

11. Technische Universität Graz

12. A-8010 Graz

13. Austria

14. Institut für Physikalische and Theoretische Chemie

15. Graz

Abstract

Five new dinuclear bridged-phenoxido dichlorido-metal(ii) complexes [M2(μ-LClO)(X)2Cl2]PF6/ClO4 complexes, where M(ii) = Co, Ni, Cu (1–4) and Zn (5); X = CH3OH, H2O or 0 were synthesized and structurally characterized. Complexes 1–4 revealed weak to moderate antiferromagnetic coupling.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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