Atomic origins of the strong metal–support interaction in silica supported catalysts

Author:

Yang Feng12ORCID,Zhao Haofei3,Wang Wu4,Wang Lei2,Zhang Lei2,Liu Tianhui2,Sheng Jian1,Zhu Sheng1,He Dongsheng5,Lin Lili6,He Jiaqing4,Wang Rongming3ORCID,Li Yan1ORCID

Affiliation:

1. Beijing National Laboratory for Molecular Science, Key Laboratory for the Physics and Chemistry of Nanodevices, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China

2. Department of Chemistry, Southern University of Science and Technology, Shenzhen, Guangdong 518055, China

3. Beijing Advanced Innovation Center for Materials Genome Engineering, Center for Green Innovation, Beijing Key Laboratory for Magneto-Photoelectrical Composite and Interface Science, School of Mathematics and Physics, University of Science and Technology Beijing, Beijing 100083, China

4. Department of Physics, Southern University of Science and Technology, Shenzhen, Guangdong 518055, China

5. Core Research Facilities, Southern University of Science and Technology, Shenzhen, Guangdong 518055, China

6. State Key Laboratory of Green Chemistry Synthesis Technology, Zhejiang University of Technology, Hangzhou 310032, China

Abstract

This work tracked at the atomic scale the interfacial reaction induced strong metal–support interaction between SiO2 and metal catalysts and evolution under reactive conditions by aberration-corrected environmental transmission electron microscopy.

Funder

National Natural Science Foundation of China

National Key Research and Development Program of China

Shenzhen Fundamental Research Program

Fundamental Research Funds for the Central Universities

Shenzhen Science and Technology Innovation Program

Natural Science Foundation of Guangdong Province

Department of Education of Guangdong Province

Southern University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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