Alkyne activation and polyhedral reorganization in benzothiazolate-capped osmium clusters on reaction with diethyl acetylenedicarboxylate (DEAD) and ethyl propiolate
Author:
Affiliation:
1. Department of Chemistry
2. Jahangirnagar University
3. Savar
4. Bangladesh
5. University College London
6. London WC1H OAJ
7. UK
8. University of North Texas
9. Denton
10. USA
Abstract
The reaction of the internal alkyne DEAD with HOs3(CO)9[μ3-C7H4NS] (1a) yields the isomeric alkenyl complexes Os3(CO)9(μ-C7H4NS)(μ3-EtO2CCCHCO2Et).
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT02933K
Reference61 articles.
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2. D. Osella and P. R.Raithby, in Stereochemistry of Organometallic and Inorganic Compounds, ed. I. Bernal, Elsevier, Amsterdam, 1988, vol. 3
3. Alkyne-substituted homo- and heterometallic carbonyl clusters of the iron, cobalt and nickel triads
4. The chemistry of [M3(CO)10(μ-dppm)](M=Ru, Os): Activating and maintaining the trinuclear core
5. A Novel Type of Carbon−Carbon Double Bond Cleavage of 1,1-Disubstituted Alkenes on a Triruthenium Polyhydrido Cluster
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2. Reactivity of unsaturated [HOs3(CO)8{µ3-Ph2PCH2PPh(C6H4)}] towards activated alkynes RC CR (R=CO2Et, CO2Me);Inorganica Chimica Acta;2021-01
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