Capturing unconventional metallofullerene M@C60 through activation of the unreactive [5,6] bond toward Diels

Capturing unconventional metallofullerene M@C60 through activation of the unreactive [5,6] bond toward Diels–Alder reaction

Published:2020 Issue:42 Volume:22 Page:24249-24256
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Wu Yabei¹²³⁴,Jiang Yuhang¹²³⁴,Deng Jianjun¹²³⁴,Wang Zhiyong¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. Renmin University of China

3. Beijing 100872

4. China

Abstract

Encapsulation of a calcium atom inside C₆₀ fullerene efficiently activates the less reactive [5,6] bond over the [6,6] bond toward Diels–Alder reaction with cyclopentadiene.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP04506C

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