Addressing molecular optomechanical effects in nanocavity-enhanced Raman scattering beyond the single plasmonic mode

Author:

Zhang Yuan12345,Esteban Ruben678910,Boto Roberto A.678,Urbieta Mattin678,Arrieta Xabier9108,Shan ChongXin12345,Li Shuzhou111213ORCID,Baumberg Jeremy J.1415161718,Aizpurua Javier678910ORCID

Affiliation:

1. Henan Key Laboratory of Diamond Optoelectronic Materials and Devices

2. Key Laboratory of Material Physics

3. Ministry of Education

4. School of Physics and Microelectronics

5. Zhengzhou University

6. Center for Material Physics (CSIC – UPV/EHU)

7. Donostia-San Sebastian

8. Spain

9. Donostia International Physics Center

10. Donostia-San Sebastian 20018

11. School of Materials Science and Engineering

12. Nanyang Technological University

13. 639798 Singapore

14. NanoPhotonics Centre

15. Cavendish Laboratory

16. University of Cambridge

17. Cambridge CB3 0HE

18. UK

Abstract

A full multimodal description of a plasmonic cavity within a continuum-field model of molecular optomechanics provides new insights into vibrational dynamics and nonlinearities of Surface-Enhanced Raman Scattering (SERS).

Funder

Eusko Jaurlaritza

European Commission

Ministerio de Ciencia e Innovación

National Natural Science Foundation of China

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science

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