Two-step spin crossover by guest-disorder induced local symmetry breaking within a 3D Hofmann-like framework-Reference-Cited by-同舟云学术

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Two-step spin crossover by guest-disorder induced local symmetry breaking within a 3D Hofmann-like framework

Published:2022 Issue:94 Volume:58 Page:13127-13130
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Windsor Hunter J.¹^ORCID,Lewis William¹²^ORCID,Neville Suzanne M.³^ORCID,Duyker Samuel G.¹²^ORCID,D’Alessandro Deanna M.¹^ORCID,Kepert Cameron J.¹^ORCID

Affiliation:

1. School of Chemistry, The University of Sydney, Sydney, New South Wales, 2006, Australia

2. Sydney Analytical, The University of Sydney, Sydney, New South Wales, 2006, Australia

3. School of Chemistry, University of New South Wales, Sydney, NSW, 2052, Australia

Abstract

A chrysene-loaded spin crossover material exhibits a two-step thermally-activated spin transition driven by guest-induced local symmetry breaking.

Funder

Australian Research Council

University of New South Wales

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC03780G

Reference24 articles.

1. Molecular magnetism: from chemical design to spin control in molecules, materials and devices

2. Spin crossover phenomena in Fe(ii) complexes

3. Molecular spin crossover phenomenon: recent achievements and prospects

4. Spin-crossover metal–organic frameworks: promising materials for designing gas sensors

5. Spin state switching in iron coordination compounds

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