Unparalleled lithium and sodium superionic conduction in solid electrolytes with large monovalent cage-like anions-Reference-Cited by-同舟云学术

Unparalleled lithium and sodium superionic conduction in solid electrolytes with large monovalent cage-like anions

Published:2015 Issue:12 Volume:8 Page:3637-3645
ISSN:1754-5692
Container-title:Energy & Environmental Science
language:en
Short-container-title:Energy Environ. Sci.

Author:

Tang Wan Si¹²³⁴⁵,Unemoto Atsushi⁶⁷⁸⁹,Zhou Wei¹²³⁴,Stavila Vitalie¹⁰¹¹¹²⁴,Matsuo Motoaki¹³⁷⁸⁹,Wu Hui¹²³⁴,Orimo Shin-ichi⁶⁷⁸⁹¹³,Udovic Terrence J.¹²³⁴

Affiliation:

1. NIST Center for Neutron Research

2. National Institute of Standards and Technology

3. Gaithersburg

4. USA

5. Department of Materials Science and Engineering

6. WPI–Advanced Institute for Materials Research (WPI–AIMR)

7. Tohoku University

8. Sendai 980-8577

9. Japan

10. Energy Nanomaterials

11. Sandia National Laboratories

12. Livermore

13. Institute for Materials Research

Abstract

Above their order–disorder transitions, both LiCB₁₁H₁₂ and NaCB₁₁H₁₂ electrolytes exhibit solid-state conductivities easily exceeding 0.1 S cm⁻¹, unmatched by any other known polycrystalline materials at these temperatures.

Funder

Japan Society for the Promotion of Science

Fuel Cell Technologies Program

Japan Science and Technology Agency

Division of Materials Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Nuclear Energy and Engineering,Renewable Energy, Sustainability and the Environment,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/EE/C5EE02941D

Reference50 articles.

1. Lithium superionic conduction in lithium borohydride accompanied by structural transition

2. Sodium ionic conduction in complex hydrides with [BH4]−and [NH2]−anions

3. Development of bulk-type all-solid-state lithium-sulfur battery using LiBH4 electrolyte

4. Lithium Fast-Ionic Conduction in Complex Hydrides: Review and Prospects

5. Complex Hydrides for Electrochemical Energy Storage

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