Merging 2,3-butanedione and N-hydroxysuccinimide as visible-light-enabled hydrogen atom transfer catalysts for CC double bond cleavage of 2-cyanoaryl acrylamides toward the synthesis of 4-amino-2-quinolones

Author:

Huang Jun1ORCID,Zhu Fengting1,Wen Jinlian1,Xu Jiali1,Yuan Jing-Mei12ORCID,Chen Wenqiang1ORCID

Affiliation:

1. Guangxi Key Laboratory of Natural Polymer Chemistry and Physics, College of Chemistry and Materials, Nanning Normal University, Nanning, Guangxi 530001, People's Republic of China

2. State key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Guangxi Normal University, Guilin, Guangxi 541004, People's Republic of China

Abstract

The CC double bond cleavage of 2-cyanoaryl acrylamides through merging 2,3-butanedione and N-hydroxysuccinimide as visible-light-enabled hydrogen atom transfer catalysts is effectively established.

Funder

Natural Science Foundation of Guangxi Province

State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education

National College Students Innovation and Entrepreneurship Training Program

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

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