A neutral vicinal silylene/phosphane supported six-membered C<sub>2</sub>PSiAu<sub>2</sub> ring and a silver(<scp>i</scp>) complex-Reference-Cited by-同舟云学术

A neutral vicinal silylene/phosphane supported six-membered C₂PSiAu₂ ring and a silver(i) complex

Published:2022 Issue:91 Volume:58 Page:12704-12707
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Nazish Mohd¹^ORCID,Bai Han²,Legendre Christina M.¹,Herbst-Irmer Regine¹^ORCID,Zhao Lili²^ORCID,Stalke Dietmar¹^ORCID,Roesky Herbert W.¹^ORCID

Affiliation:

1. Institut für Anorganische Chemie, Universität Göttingen, Tammannstrasse 4, Göttingen, 37077, Germany

2. Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing, 211816, China

Abstract

We report on the hybrid bidentate silylene and phosphane ligand (1) stabilized Au which are capable of forming a gold containing six-membered ring (2). 2 exhibits an intramolecular aurophilic interaction, which is supported by DFT calculations.

Funder

Danmarks Grundforskningsfond

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Province

Nanjing Tech University

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC04163D

Reference59 articles.

1. Synthesis and Characterization of [PhC(NtBu)2]SiCl: A Stable Monomeric Chlorosilylene

2. High Yield Access to Silylene RSiCl (R = PhC(NtBu)2) and Its Reactivity toward Alkyne: Synthesis of Stable Disilacyclobutene

3. Striking Stability of a Substituted Silicon(II) Bis(trimethylsilyl)amide and the Facile Si–Me Bond Cleavage without a Transition Metal Catalyst

4. Preparation, structure and catalytic properties of a binuclear Pd(0) complex with bridging silylene ligands

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