Me<sub>2</sub>(CH<sub>2</sub>CH)SiCN: a bifunctional ethylene equivalent for Diels–Alder reaction based controllable tandem synthesis-Reference-Cited by-同舟云学术

Me₂(CH₂CH)SiCN: a bifunctional ethylene equivalent for Diels–Alder reaction based controllable tandem synthesis

Published:2022 Issue:12 Volume:13 Page:3519-3525
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wu Wen-Biao¹,Mu Bo-Shuai¹,Yu Jin-Sheng¹²^ORCID,Zhou Jian¹²³^ORCID

Affiliation:

1. Shanghai Engineering Research Center of Molecular Therapeutics and New Drug Development, Shanghai Key Laboratory of Green Chemistry and Chemical Processes, East China Normal University, Shanghai 200062, China

2. Key Laboratory of Tropical Medicinal Resource Chemistry of Ministry of Education, Hainan Normal University, Haikou 571158, China

3. Institute of Eco-Chongming, Shanghai 202162, China

Abstract

We report an unprecedented tandem Wittig/cyanosilylation/DA reaction/retro-cyanosilylation/isomerization sequence by using our designed bifunctional ethylene equivalent Me2(CH2CH)SiCN.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Science and Technology Innovation Plan Of Shanghai Science and Technology Commission

Ministry of Education of the People's Republic of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/SC/D2SC00147K

Reference83 articles.