Panchromatic light harvesting and record power conversion efficiency for carboxylic/cyanoacrylic Fe(ii) NHC co-sensitized FeSSCs

Author:

Reddy-Marri Anil1ORCID,Marchini Edoardo2ORCID,Cabanes Valentin Diez3ORCID,Argazzi Roberto4,Pastore Mariachiara3ORCID,Caramori Stefano2ORCID,Gros Philippe C.5ORCID

Affiliation:

1. Department of Chemistry, North Carolina State University, 851 Main Campus Drive, Raleigh, North Carolina, 27695-8204, USA

2. Department of Chemical and Pharmaceutical Sciences, University of Ferrara, Via L. Borsari 46, 44121, Ferrara, Italy

3. Université de Lorraine, CNRS, LPCT, F-54000 Nancy, France

4. CNR-ISOF c/o Department of Chemical, Pharmaceutical and Agricultural Sciences, University of Ferrara, Via L. Borsari 46, 44121, Ferrara, Italy

5. Université de Lorraine, CNRS, L2CM, F-54000 Nancy, France

Abstract

The co-sensitization of TiO2 by using a combination of carboxylic and thienylcyanoacrylic (ThCA)–Fe(ii) pyridyl-NHC sensitizers produced a panchromatic absorption and the best photocurrent and efficiency ever reported for an FeSSC.

Funder

Agence Nationale de la Recherche

Università degli Studi di Ferrara

European Regional Development Fund

Université de Lorraine

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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