Efficient acceptorless dehydrogenation of secondary alcohols to ketones mediated by a PNN-Ru(ii) catalyst-Reference-Cited by-同舟云学术

Efficient acceptorless dehydrogenation of secondary alcohols to ketones mediated by a PNN-Ru(ii) catalyst

Published:2017 Issue:8 Volume:7 Page:1654-1661
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Wang Zheng¹²³⁴⁵,Pan Bing⁵⁶⁷⁴,Liu Qingbin⁵⁶⁷⁴,Yue Erlin¹²³⁴,Solan Gregory A.¹²³⁴⁸^ORCID,Ma Yanping¹²³⁴,Sun Wen-Hua¹²³⁴⁹^ORCID

Affiliation:

1. Key Laboratory of Engineering Plastics and Beijing National Laboratory for Molecular Science

2. Institute of Chemistry, Chinese Academy of Sciences

3. Beijing 100190

4. China

5. College of Chemistry and Material Science

6. Hebei Normal University

7. Shijiazhuang 050024

8. Department of Chemistry

9. CAS Research/Education Center for Excellence in Molecular Sciences

Abstract

The ruthenium(ii) complex, [fac-PN_HN]RuCl₂(PPh₃) (C), in combination with t-BuOK proved an effective and versatile catalyst allowing aromatic-, aliphatic- and cycloalkyl-containing alcohols to be efficiently converted to their corresponding ketones with high values of TON achievable.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CY/C7CY00342K

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